RPSC 2nd Grade Teacher Exam 2014 Chemistry Graduate standard Syllabus


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Chemistry :

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1                    Zero group elements : Position in periodic table, isolation, compounds of zero group elements.

2                    d-block elements : Electronic configuration, general characteristics for e.g. colour, oxidation state, tendency to form complexes, magnetic properties, interstitial compound, catalytic properties, alloys.

3                    f-block elements : Lanthanides and Actinides, Electronic configuration, Lanthanide contraction and its consequences, Super heavy elements.

4                    Bio-Inorganic Chemistry : Role of bulk and trace metal ions in biological system with special reference to Mg, Ca, Fe and Cu.

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Reaction Mechanism : Inductive, Mesomeric and Hyper – conjugation. Addition and   substitution   :
  Electrophilic addition and substitution reaction, Nucleophilic addition and substitution reactions (SN1
  and SN2), Elimination reactions.

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Spectroscopy Techniques :
  UV-Visible : Lambert-Beer’s law, Auxochrome and Chromophore, various shifts, calculation of
  λmax values of dienes, polyenes and enone compounds.
  IR : Molecular vibrations, Hook’s law, intensity and position of IR bands, finger print region,
  characteristic absorption of common functional groups.
  NMR : Proton magnetic resonance (1H NMR) spectroscopy, nuclear shielding and de-shielding,
  chemical shift and spin-spin coupling, interpretation of 1H NMR spectra of simple organic
  compounds.

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Chemical Kinetics : Order and Molecularity of reactions, first and second order reactions  and  their
  rate expressions (no derivation), Zero and Pseudo order reactions, Arrhanius euqtion, Collision theory
  and activated  complex theory.

 

8                    Solutions : Osmotic pressure, Lowering of vapour pressure, depression of freezing point and elevation of boiling point. Determination of molecular weight in solution. Association and dissociation of solutes.

9                    Electrochemistry : Electrochemical cells, electrode potentials, measurement of e.m.f. Conductance :

Cell constant, specific and equivalent conductivity, Kohlrausch’s Law and its applications, solubility
and solubility product, equivalent conductivity at infinite dilution of weak electrolytes, hydrolysis and
hydrolysis constant.  
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