1 Zero group elements : Position in periodic table, isolation, compounds of zero group elements.
2 d-block elements : Electronic configuration, general characteristics for e.g. colour, oxidation state, tendency to form complexes, magnetic properties, interstitial compound, catalytic properties, alloys.
3 f-block elements : Lanthanides and Actinides, Electronic configuration, Lanthanide contraction and its consequences, Super heavy elements.
4 Bio-Inorganic Chemistry : Role of bulk and trace metal ions in biological system with special reference to Mg, Ca, Fe and Cu.
|Reaction Mechanism : Inductive, Mesomeric and Hyper – conjugation. Addition and substitution :|
|Electrophilic addition and substitution reaction, Nucleophilic addition and substitution reactions (SN1|
|and SN2), Elimination reactions.|
|Spectroscopy Techniques :|
|UV-Visible : Lambert-Beer’s law, Auxochrome and Chromophore, various shifts, calculation of|
|λmax values of dienes, polyenes and enone compounds.|
|IR : Molecular vibrations, Hook’s law, intensity and position of IR bands, finger print region,|
|characteristic absorption of common functional groups.|
|NMR : Proton magnetic resonance (1H NMR) spectroscopy, nuclear shielding and de-shielding,|
|chemical shift and spin-spin coupling, interpretation of 1H NMR spectra of simple organic|
|Chemical Kinetics : Order and Molecularity of reactions, first and second order reactions and their|
|rate expressions (no derivation), Zero and Pseudo order reactions, Arrhanius euqtion, Collision theory|
|and activated complex theory.|
8 Solutions : Osmotic pressure, Lowering of vapour pressure, depression of freezing point and elevation of boiling point. Determination of molecular weight in solution. Association and dissociation of solutes.
9 Electrochemistry : Electrochemical cells, electrode potentials, measurement of e.m.f. Conductance :
|Cell constant, specific and equivalent conductivity, Kohlrausch’s||Law and its applications, solubility|
|and solubility product, equivalent conductivity at infinite dilution of weak electrolytes, hydrolysis and|
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